Wow! Just toss that old valve. They don't make good trims for that anymore. You can't use the PolyB connections either .
If you repiping with PEX, you will want to run PEX to the new valve, making sure that the tub spout remains copper if you using a slip fit spout, or if it's a threaded spout, perhaps a drop ear 90 with a nipple pointing out for a spout. Brass and not galvanized.
Galvanized gives you a little bit of rusty water every morning, brass doesn't and a copper slip fit doesn't either.
The old Moen valve you have hasn't been a legal valve in decades. The new ones are either pressure balanced or Thermostatic to prevent temperature swings.