FYI - Just stating the obvious
Unions typically have rubber or similar gaskets. If you have chlorinated city water, not a good recipe for long term success. Chlorinated water eats rubber gaskets for lunch. In my city, you can smell chlorine in the water in the early morning hours. Look for parts with no rubber. SharkBites and Pro Press fittings have 2 or more rubber O-rings. Steer clear.......
Ball valves like what you linked are water hammer makers. Unless you gently slash SLOWLY close/open them. Gate valves are better. They open and close much slower. Not such a big deal for houses. On a 6" main or larger, no ball valves are used. So look for a gate valve.
Lastly look for a valve that already has the connections you need. Adding adapters equates to more failure (leaks) points and cost slash complexity. Keep it simple as possible.
There are many out there to pick from. One from Hope Cheapo below.
The Plumber s Choice - 3/4 Full Port PEX Barb Ball Valve Water Shut Off with Tee Handle - this product is as convenient to use as it is durable.
www.homedepot.com