So, you really went for
beyond-ridiculous oversizing factor, eh? The CGa-6 has enough output to heat a 10,000+ square foot house at 0F outdoor temps, and probably enough BTUs per hour to heat your house at an outdoor temperature of absolute zero (theoretically, since the natural gas itself would already be long since frozen). ASHRAE recommends 1.4x oversizing for the load at the 99th percentile temperature bin, which is usually enough to cover the coldest hours of the past century. At your likely 5x-6x-7x oversizing the only advantage is the speed of recovery from overnight setbacks (assuming you have enough radiation to even deliver that much heat), and with an atmospheric drafted cast iron boiler that amount of oversizing knocks between 10-15% off the AFUE numbers for your as-used efficiency. (AFUE testing is at 1.7x oversizing.)
A
right-sized narrowing liner may or may not be a local code requirement, but is ALWAYS a good idea at 83% efficiency and higher. An 8" x 8" clay liner can handle over 300,000 BTU/hr of ~83-84% efficiency burner if it has a reasonably high duty cycle, but at your oversizing factor the average duty cycle won't be high enough to warm much terra-cotta liner to above the dew point of the exhaust in dead of winter. The lower exhaust temperature that comes with 83-84% efficiency compared to your old 80% or lower efficiency Burnham means it will be substantially more susceptible to flue condensation. If the chimney is on the exterior of the house and exposed to outdoor air temps this is substantially bigger problem than if the chimney runs up through the middle of the house surrounded by warm conditioned space air, with only a cold attic and a few feet of above-roof exposure, but even interior chimneys are prone to condensation when the duty cycle is that low.
Adding up the total BTU capacity requirement, the CGa-6 is 175,000 BTU/hr, the water heater is likely to be 35-45,000BTU/hr (look it up), which adds up to something on the order of 200-225K. Do not oversize the liner- you're looking for the smallest liner that fills the bill, since that exposes less condensing surface to the exhaust, and increases the stack velocity.
The CGa-6 is 175,000 BTU/hr, the water heater is likely to be 35-45,000BTU/hr (look it up), which adds up to something on the order of 200-225K. If the top of the flue is at least 20' above the vent port for the boiler, a 6" liner is about right. Single-walled or B-vent can be used if it's an interior chimney, but if it's an exterior chimney a single wall liner has to be stainless to tolerate the condensation (see p.8 of
the manual.)
You might find
this slide show covering the fundamentals useful to review (starting at around slide #25, but pay particular attention to slide #43 & #44)