In case you're worried that the 44,000 BTU/hr output of the CGa-25 might leave you cold, consider this:
With only 65' of baseboard on the main zones, at the water temps most systems are being run at (170-180F AWT), the baseboard can only deliver ~35-40,000 BTU/hr. If the system was able to keep up with the Polar Vortex events of the past couple of winters, the CGa-25 would also be able to keep up with the living space no matter what. During extreme cold events the worst that would happen is that you may need to lower the temp in the basement to something less than 68F to keep the other two zones at 70F so that the boiler is only serving the upstairs zones.
Odds are that even that won't be necessary, but it's much better for both efficiency and wear and tear on the boiler to not oversize it for the radiation. The CGa-3 would be ~3x oversized for any one zone, but the CGa-25 would be only(?) 2x oversized for any single zone, and would see far fewer and somewhat longer burn cycles, and would likely hit it's AFUE numbers.
Once it's up and running, as part of the commissioning process it's worth measuring the minimum burn time and burns per hour for when serving a single zone. Setting up the boiler controls for the maximum possible differential (and at a fairly high temp) would help on both burn-time and numbers of burns. Burn lengths shorter than 5 minutes deliver a measurably lower efficiency, and more than 5 burns/hour puts wear & tear on the ignition system, but depending on the actual thermal mass on the zone plumbing you may still do OK despite 2x oversizing for the radiation , but it's probably not possible not at 3x. If the measured numbers indicate that it'll be doing a lot of short-cycling, it will be worth installing a heat-purging economizer control (a ~$200 part, easily DIY-able for a licensed electrician) to maximally utilize the available thermal mass. This is roughly how it pencils out based on best-guesstimates.
The boiler itself has 1.5 gallons, or abou 12 lbs of water in it plus about 17-18 lbs "water equivalent" of thermal mass in the cast iron. Assuming it's all 3/4" copper, and the main zone radiation + plumbing adds up to about 100', you have another ~20 lbs of water in the zone plumbing, for a total of about 50 lbs of thermal mass.
If the differential from low limit to high limit is set to 20F, it takes 50 lbs x 20F= 1000 BTU of excess boiler output to make that swing. At 44,000 BTU/hr of boiler output, with the zone emitting about 20,000 BTU/hr, that's 24,000 BTU/hr of excess, and it only takes 1000/24,000 of an hour to slew the system temp 20F, which is 2.5 minutes. With a heat purging control you can get much bigger low-to-high swings than with most aquastat type boiler control setups, so if you program the low-limit to 130F (so that it won't condense inside the boiler) and leave the high limit at 180F or higher, you should be able to get 5+ minute burns out of the CGa-25 with the economizer control under all load conditions.
But with the 59,000 BTU/hr output of the CGa-3 you would have ~40,000 BTU/hr of "extra" heat being dumped into the zone plumbing in stead of 24,000 , and would end up with (60 x 1000/40,000=) 1.5 minute burn times at a 20F differential, cutting severely into efficiency. An economizer control would still cut the number of burns, but would not be able to lengthen the minimum burn times to more than something like 3-4 minutes. While that's a heluva lot better than 1.5 minutes, it isn't long enough to hit it's efficiency numbers. To make the CGa-3 hit it's numbers you'd either have to increase the radiation, or increase the thermal mass.
This is just the napkin math version of the basic problem but it's close enough to reality to know that with your radiation you'll be lot better off with the smaller boiler.