When plumbed in Series, cold water will always enter the 1st tank so its electric heating elements will be utilized 100% of the time. As hot water will exit the 1st tank and flow to the 2nd tank, with identical temperature settings for both tanks. the 2nd tank's electric heating elements will be only utilized when the 1st tank's capacity has been depleted which will result in cooler water entering the 2nd tank. The 2nd tank will then mostly provide additional hot water storage, but minimal heating capacity to reduce recovery time.
When plumbed in Parallel as shown in Fitter30's drawing, each heater will always supply 50% of hot water consumed. Since cold water will equally enter each tank, the heating element run time will be equalized between both tanks and the recovery rate will be doubled.
If the water contains sufficient minerals for scale accumulation to be a concern, suggest then installing a water softener system to remove calcium and Magnesium minerals which are the most common cause of scale formation.