Pressure can be broken down to a couple of factors:
- static pressure: this will be the same, regardless of how it is plumbed. It is based on the supply +/- and gravity effects which amount to 0.43#/foot of elevation change- drops as you go up, rises when you go down.
- dynamic pressure: this will be affected by several things including, the type of pipe used, the ID, the number of fittings (which includes straight, and any angles, the length of the run, and the volume as the higher the volume, the more friction becomes an issue
Pex is better than say copper for friction effects, but can be severely affected because its ID is smaller than copper in the same nominal size (the nominal OD is the same on both, but the ID differs to compensate for the strength of the material).
How much a single elbow will affect the dynamic pressure can be looked up in tables for the specified materials. I don't remember that off the top of my head. One elbow won't change the dynamic pressure all that much.
The dynamic pressure could contribute to your satisfaction overall. If volume is an issue, using a larger pipe is called for verses coper.
One of the major advantages of pex is that because it bends easily (just don't exceed the maximum bend radius - you can use a bend support bracket to ensure that) which often allows you to eliminate any fitting where one would be required with copper. IOW, while it may not look 'neat', it often can work by just bending the pipe so it is in the proper orientation.