A couple of points...depending on how it is setup, and used, modern condensing boilers may never actually condense the exhaust gasses. Second, the exhaust flue needs to be sloped back to the boiler, as described and pictured in the installation manual. Third, the condensate will be somewhat acidic, so depending on where it is actually discharged, it may benefit from neutralization. To condense, the supply and return water in the boiler needs to be much lower in temperature than in a conventional install. If it was not setup this way, it will not condense, and thus, won't be as efficient as it could be (assuming the load doesn't require it to be that hot). A CI boiler generally needs to run hotter, as condensing mode will cause excessive wear and erosion in the heat exchanger. It may condense momentarily or on a short fire, but should not be doing it regularly or it won't last long. Normally, the flue gasses will be hot enough so that they won't condense except maybe just when it first starts out.