For looks, I'll vote for copper every time. If you're not too far from the ocean, it will develop a nice green patina if exposed to the salt air. Otherwise, it will turn a dark reddish brown color over time.
Yeah, put some effort into allowing the system to drain over the winter. Remember that the riser up to the shower head will stay full of water all the time unless you provide drainage for that also. One way would be to set the valve up as if for a tub/shower install and use the tub outlet to drain the riser, perhaps with a shut-off of some sort. There are several options there.
Didn't mean to be rude earlier. The wife trying to drag me into her HGTV world while I'm trying to post. Anyway, if you drive through the country where I grew up, you'll see a lot of bare well tanks standing uncovered out in the yards of the folks who have their own well. This would be around latitude 31, Florida state line. Two hundred miles north of there, my current bailiwick, all the well tanks are in insulated well houses, where in winter the wise turn on a shop light in there with a 100w bulb close to the pressure switch, to keep things from freezing.
It snowed down there one time in 1958, and again in 1973, as I recall. This is a couple of hundred miles north of Daytona.